https://bugs.winehq.org/show_bug.cgi?id=51051
--- Comment #10 from Rafał Mużyło galtgendo@o2.pl --- Unless ebuild enforces it differently (my reading of the build says it's not the case here), portage will use whatever compiler is set as default unless the user has custom settings for the package.
So, for most people on Gentoo, unless they've set 'mingw' useflag and/or set their default compiler to clang, it's still non-PE build with gcc. LTO is an explicit user's choice, as nothing about it is in the ebuild.